# HG changeset patch # User muon-spectroscopy-computational-project # Date 1699976122 0 # Node ID f59731986b616b0853ae156be19b2638c598734b planemo upload for repository https://github.com/MaterialsGalaxy/larch-tools/tree/main/larch_lcf commit 5be486890442dedfb327289d597e1c8110240735 diff -r 000000000000 -r f59731986b61 common.py --- /dev/null Thu Jan 01 00:00:00 1970 +0000 +++ b/common.py Tue Nov 14 15:35:22 2023 +0000 @@ -0,0 +1,46 @@ +from typing import Iterable + +from larch.io import extract_athenagroup, read_athena +from larch.io.athena_project import AthenaGroup +from larch.symboltable import Group +from larch.xafs import autobk, pre_edge, xftf + + +def get_group(athena_group: AthenaGroup, key: str = None) -> Group: + if key is None: + group_keys = list(athena_group._athena_groups.keys()) + key = group_keys[0] + return extract_athenagroup(athena_group._athena_groups[key]) + + +def read_group(dat_file: str, key: str = None, xftf_params: dict = None): + athena_group = read_athena(dat_file) + group = get_group(athena_group, key) + bkg_parameters = group.athena_params.bkg + print(group.athena_params.fft) + print(group.athena_params.fft.__dict__) + pre_edge( + group, + e0=bkg_parameters.e0, + pre1=bkg_parameters.pre1, + pre2=bkg_parameters.pre2, + norm1=bkg_parameters.nor1, + norm2=bkg_parameters.nor2, + nnorm=bkg_parameters.nnorm, + make_flat=bkg_parameters.flatten, + ) + autobk(group) + if xftf_params is None: + xftf(group) + else: + print(xftf_params) + xftf(group, **xftf_params) + xftf_details = Group() + setattr(xftf_details, "call_args", xftf_params) + group.xftf_details = xftf_details + return group + + +def read_groups(dat_files: "list[str]", key: str = None) -> Iterable[Group]: + for dat_file in dat_files: + yield read_group(dat_file=dat_file, key=key) diff -r 000000000000 -r f59731986b61 larch_lcf.py --- /dev/null Thu Jan 01 00:00:00 1970 +0000 +++ b/larch_lcf.py Tue Nov 14 15:35:22 2023 +0000 @@ -0,0 +1,82 @@ +import json +import sys + +from common import read_group + +from larch.math.lincombo_fitting import get_label, lincombo_fit +from larch.symboltable import Group + +import matplotlib +import matplotlib.pyplot as plt + + +def plot( + group_to_fit: Group, + fit_group: Group, + energy_min: float, + energy_max: float, +): + formatted_label = "" + for label, weight in fit_group.weights.items(): + formatted_label += f"{label}: {weight:.3%}\n" + + plt.figure() + plt.plot( + group_to_fit.energy, + group_to_fit.norm, + label=group_to_fit.filename, + linewidth=4, + color="blue", + ) + plt.plot( + fit_group.xdata, + fit_group.ydata, + label=formatted_label[:-1], + linewidth=2, + color="orange", + linestyle="--", + ) + plt.grid(color="black", linestyle=":", linewidth=1) # show and format grid + plt.xlim(energy_min, energy_max) + plt.xlabel("Energy (eV)") + plt.ylabel("normalised x$\mu$(E)") # noqa: W605 + plt.legend() + plt.savefig("plot.png", format="png") + plt.close("all") + + +def set_label(component_group, label): + if label is not None: + component_group.filename = label + else: + component_group.filename = get_label(component_group) + + +if __name__ == "__main__": + # larch imports set this to an interactive backend, so need to change it + matplotlib.use("Agg") + prj_file = sys.argv[1] + input_values = json.load(open(sys.argv[2], "r", encoding="utf-8")) + + group_to_fit = read_group(prj_file) + set_label(group_to_fit, input_values["label"]) + + component_groups = [] + for component in input_values["components"]: + component_group = read_group(component["component_file"]) + set_label(component_group, component["label"]) + component_groups.append(component_group) + + fit_group = lincombo_fit(group_to_fit, component_groups) + print(f"Goodness of fit (rfactor): {fit_group.rfactor:.6%}") + + energy_min = input_values["energy_min"] + energy_max = input_values["energy_max"] + if input_values["energy_format"] == "relative": + e0 = group_to_fit.e0 + if energy_min is not None: + energy_min += e0 + if energy_max is not None: + energy_max += e0 + + plot(group_to_fit, fit_group, energy_min, energy_max) diff -r 000000000000 -r f59731986b61 larch_lcf.xml --- /dev/null Thu Jan 01 00:00:00 1970 +0000 +++ b/larch_lcf.xml Tue Nov 14 15:35:22 2023 +0000 @@ -0,0 +1,63 @@ + + perform linear combination fit on XAS data + + + 0.9.71 + + 0 + + + 10.1088/1742-6596/430/1/012007 + macros.xml + + + + + + xraylarch + matplotlib + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + @TOOL_CITATION@ + 10.1107/S0909049505012719 + + \ No newline at end of file diff -r 000000000000 -r f59731986b61 macros.xml --- /dev/null Thu Jan 01 00:00:00 1970 +0000 +++ b/macros.xml Tue Nov 14 15:35:22 2023 +0000 @@ -0,0 +1,26 @@ + + + + + + + + + + + + + + + + + + + + + + + + + + \ No newline at end of file diff -r 000000000000 -r f59731986b61 test-data/PtSn_OCO_Abu_1.prj Binary file test-data/PtSn_OCO_Abu_1.prj has changed diff -r 000000000000 -r f59731986b61 test-data/SnO2_extracted.prj Binary file test-data/SnO2_extracted.prj has changed diff -r 000000000000 -r f59731986b61 test-data/Sn_foil_extracted.prj Binary file test-data/Sn_foil_extracted.prj has changed